MONITORING OF PESTICIDES AND THEIR METABOLITES

The definition of pesticide residues (including their metabolites) is essential for the evaluation of compliance to Maximum Residue Levels in food and drink and for surveillance programmes assessing compliance with these standards.

The recent advances in analytics, together with the evolution of regulatory needs and guidance documents have driven the development of monitoring approaches in both environmental and food/feed matrices. In fact, the achievement of such monitoring results is a fundamental step in authorization decisions although inborn challenges have been posed. With this regard, the guidance documents on pre- and post-registration pesticide monitoring pose several critical questions on fitness-for-purposes and demand for robust, effective and sensitive methods overcoming matrix effects and covering both parent compounds and their metabolites. In this framework, either target or untargeted approaches showed some limitation together with inherent advantages, still highlighting the need for future improvement.

This session focuses on novel, effective and comprehensive approaches towards the reliable and accurate monitoring of pesticides and their transformation products into environmental compartments or food/feed commodities.

 

Session Chairs

Ingeborg Joris (VITO, Belgium)

Nicoleta Alina Suciu (Università Cattolica del Scaro Cuore, Italy)

 

Program: September 3 – 15:40 – 17:40

 

Oral Presentations

182 –“From plot to catchment scale: contamination of different water types with metazachlor – and flufenacet metabolites” – Uta Ulrich, Kiel University (Deutschland)

283 – “Conducting groundwater monitoring studies in Europe for pesticide active substances and theirmetabolites in the context of regulation (EC) 1107/2009”Anne Louise Gimsing, The Danish Environmental Protection Agency (Denmark)

232 –“Evaluation of the role of dissolved and particulate phases in Chlordecone contamination in rivers” – Samouelian Anatja, INRA (France)

284 – “Biogenic residue formation from pesticides in soil: Determination of Dithiocarbamate Fungicides and of their degradation products in fruits andvegetables by a multi approach strategy” – Alin Constantin DIRTU, ANSES (France)

253 – “HRAM-tools for studies of pesticide metabolites in the soil environment” – Marit Almvik, Norwegian Institute of Bioeconomy Research (Norway)

256 – “Potential use or limitations of the reuse of reclaimed water in the production of vegetable foods” – M. J. Martínez-Bueno, University of Almeria (Spain)

 

Poster Presentations

1 “Pesticides in Africa air” – Céline Degrendele, RECETOX (Czech Republic)

2 “Preliminary results from an in-depth study on pesticide exposure of children living in the rural Western Cape, South Africa” – Céline Degrendele, RECETOX (Czech Republic)

186 “Assessing kinetics of low level metabolites” – Simon Ford, Battelle UK Limited (UK)

188 “Lipophilicity matters – a new glance at experimental TSCF data from literature” – Marion Beckmann, Bayer AG (Deutchland)

190 “Plant Uptake – Results and status of regulatory predictions and experiments” – Herbert Resseler, Syngenta Agro Gmbh (Deutchland)

191 “Herbicide transformation in different agricultural soil types and depths” – Sandra Willkommen, Kiel University (Deutchland)

193 “Consideration of plant growth to derive a foliar DT50 suitable as input for modelling – Foliar application to spring wheat during BBCH 31 to 59” Gerald Reinken, Bayer AG (Deutchland)

206 “Increasing the persistence of allelochemicals in soil for their potential use as biopesticides” –Beatriz Gámiz, CSIC (Spain)

207 “A monitoring study of triazole-fungicides and leaching of 1,2,4-triazole to drainage and groundwater” – Nora Badawi, GEUS (Denmark)

222 “Long-term root uptake of trifluoroacetic acid (TFA) by winter wheat during a whole vegetation period” – Marion Beckmann, BAYER AG (Deutchland)

226 “Using a higher-tier coupled modelling approach to support the evaluation of groundwater monitoring studies” Wenkui He, Knoell Germany GmbH (Deutchland)

237 “The compounds glycyrrhizic acid as fungicides of the diseases of wheat” – Kushiev Khabibjon, Gulistan State University

240 “ARPA SICILIA: impatto di alcuni pesticidi sulle acque interne siciliane nel periodo 2013-2017” – Anna Abita, ARPA Sicilia (Italy)

242 “Occurrence and context associated with monitoring of triflusulfuron methyl in the groundwater in Italy” – Neil Mackay, FMC AGRO LTD (UK)

243 “Developing a long-term exposure monitoring for PPP residues in Swiss soils” – Levke Godbersen, Swiss National Soil Monitoring Network (Switzerland)

251 “Development of a method for the determination of pesticides in avocado fruit by QuEChERS and liquid chromatography-mass spectrometry. Analysis of field samples” – Pilar Sandín –España, INIA (Spain)

276 “Simulation of the long-term evolution of pesticide concentrations in the Zwischenscholle aquifer using the coupled soil-groundwater model MODFLOW-HYDRUS-MT3DMS” – Jan Vanderborght, Forschungszentrum Jülich (Belgium)

285 “Advice and voluntary action help keep water clean” – Steven Bailey, Natural England (UK)

292 –“Pesticide monitoring and good agricultural practices evaluation in surface and ground water bodies focused on the pineapple production in the north zone of Costa Rica” – Greivin Mauricio Pérez Rojas, CICA, Universidad de Costa Rica (Costa Rica)

299 “Pesticide Occurrence and Water Quality Assessment from an Agricultural Influenced Tropical Region – Didier Daniel Ramírez Morales, Universidad de Costa Rica (Costa Rica)

318 –“Copper presence in groundwater of Tidone Valley, an area with intensive viticulture” – Roberta Zambito Marsala, Catholic University of the Sacred Heart (Italy)

319 Occurrence of pyrethroids and chlorpyrifos in various products representing Czech food basket” – Petr Mraz, University of Chemistry and Technology, Prague (Czech Republic)

358 –“Work of a SETAC Group on Groundwater Monitoring: Vulnerability Assessment and Site Characterisation” Benedict Miles, BASF SE (Germany)

359 “Work of a SETAC group on groundwater monitoring: Use of publicly available groundwater monitoring data in risk assessment” – Anne Louise Gimsing, The Danish Environmental Protection Agency (Denmark)

360 “Work of a SETAC Group on Groundwater Monitoring: Monitoring Study Designs” – Andrew Newcombe, Arcadis (USA)

390 “Public Monitoring Data Compilation for Assessing Fate and Transport of Plant Protection Products: Insights, Challenges, and Opportunities” – Andrew Newcombe, Arcadis (USA)